The injection molding process was not properly cured. How should I select the product liquid silicone rubber 9250-40B?
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One cannot simply conclude that product liquid silicone 9250-40B is suitable for all computer keypads, keyboard protective covers, seals, mobile phone cases, or glass fiber surface coating systems based solely on its good elasticity, resistance to heat aging, or the fact that it can be left at room temperature for 72 hours after mixing. The correct judgment should involve confirming the A/B mixing ratio, mixing uniformity, defoaming process, injection or coating conditions, curing temperature and time, substrate type, environmental cleanliness, and dilution ratio. Then, determine whether the problem is caused by platinum catalyst poisoning, uneven mixing, insufficient curing, or poor compatibility with the substrate and molding process. Product 9250-40B can be considered as a candidate for injection/molding liquid silicone, but it must undergo small-scale tests, curing verification, and actual working condition confirmation.
Why does thermosetting liquid silicone often exhibit poor curing in injection molding or coating?
If the A/B components are not accurately measured in a 1:100 ratio or are not mixed evenly, resulting in insufficient crosslinking density or incomplete curing.
The rubber material comes into contact with compounds such as As, Hg, Sn, N, P, S, etc., causing platinum catalyst poisoning and resulting in poor or incomplete curing.
Although it can be left at room temperature for 72 hours after mixing, if it exceeds the applicable period or the storage temperature is inappropriate, the rubber material's activity and fluidity decrease.
Insufficient vacuum defoaming, with residual bubbles in the injection component or coating, affecting appearance, mechanical properties, and sealing performance.
Inconsistent injection temperature, mold temperature, or curing time with the product thickness leads to insufficient curing or over-curing.
The substrate surface is not cleaned or has oil stains, release agents, or residual additives, affecting the coating adhesion and uniformity.
Improper dilution ratio or diluent selection affects the self-extinguishing V0 condition of the glass fiber surface coating.
When switching from other liquid silicone, mixtures, or coating materials, the A/B ratio, defoaming, and curing conditions are not adjusted.
Improper storage conditions or exceeding the 120-day storage period leads to a decrease in the activity of the A/B components, affecting the consistency of curing.
The injection machine, mold, or metering equipment has dead zones or cross-contamination, causing platinum catalyst poisoning or batch fluctuations.
In electronic industrial fiberglass coatings, the thickness and curing conditions of the diluted coating are not verified according to the self-extinguishing V0 requirements.
The textile or electronic substrates have limited temperature resistance, and the curing temperature does not match the substrate's tolerance.
First, determine at which stage the curing or molding problem occurs.
Failure stage Possible causes Priority inspection direction
Not curing or incomplete curing after mixing A/B ratio deviation, mixing unevenness, platinum catalyst poisoning Accuracy of measurement, mixing efficiency, environmental cleanliness
Surface stickiness or slow curing of injection components Malfunctioning mold temperature, catalyst poisoning, expired rubber material Mold temperature, substrate and contaminants, storage conditions
Presence of bubbles or voids in injection components Insufficient defoaming, inappropriate injection speed or pressure, poor mold exhaust Defoaming process, injection parameters, mold exhaust
Insufficient hardness or strength of the product Low crosslinking density, A/B ratio deviation, insufficient curing A/B ratio, curing temperature and time
Poor coating adhesion or peeling Unclean substrate, excessive coating thickness, insufficient curing Surface treatment, coating thickness, curing conditions
Self-extinguishing V0 of fiberglass coating not reached Improper dilution ratio, coating thickness, curing degree Dilution process, coating thickness, flame retardant verification
Batch-to-batch curing or performance fluctuations A/B component activity differences, storage conditions, measurement error Incoming inspection, storage records, measurement accuracy
Does not cure after contact with substances such as Sn, Hg, As, etc. Catalyst poisoning Substrate, pigment, source of equipment contamination
If only focusing on "whether product 9250-40B was used", without recording the A/B ratio, defoaming, injection/molding conditions, substrate and contaminant control, it is usually difficult to accurately determine whether it is a material problem or a process problem.
Why is it not necessarily effective to merely increase the curing temperature or increase the A/B ratio?
Product 9250-40B plays a role in platinum addition curing in the system. It is influenced by the A/B ratio, degassing, curing temperature, substrate, and catalyst poisons. Simply increasing the temperature or the amount may cause side effects.
Raising the mold temperature or curing temperature may lead to over-sulfurization on the surface or damage to the substrate, while the interior has not fully cured.
Increasing the total amount of A/B does not change the 1:100 ratio requirement. Excessive adhesive will not increase the crosslinking density; instead, it causes waste.
Extending the curing time may improve deep curing, but it may affect production efficiency and the demolding performance of the product.
Increasing the dilution ratio may improve the coating thickness and feel, but it may reduce self-extinguishing ability and protective performance.
After platinum catalyst poisoning, increasing the temperature or extending the curing time cannot achieve normal curing.
When the substrate surface is not cleaned, adjusting the curing conditions alone cannot solve the adhesion problem.
When degassing is insufficient, increasing the temperature may cause bubble expansion, affecting the appearance and performance of the product.
When the mixture exceeds the applicable period or is stored improperly, adjusting the curing conditions alone cannot restore the original performance.
Therefore, when optimizing, one should observe the A/B ratio, degassing, curing conditions, substrate treatment, pollutant control, and coating thickness, rather than only adjusting a single parameter.
What are the differences between Product 9250-40B and similar liquid silicone resins or molding schemes in terms of selection?
Comparison direction Product 9250-40B (addition molding/liquid silicone resin coating) Product B11 (addition molding liquid silicone resin) Mixing rubber injection molding General condensation type silicone resin Selection boundary
Curing mechanism Platinum catalytic addition molding, A/B = 1:100 Platinum catalytic addition molding, A/B = 1:100 Peroxide or addition molding Humid gas condensation curing Depends on molding method and substrate selection
Operating temperature -40℃~250℃ -40℃~250℃ Different for each formula Generally High-temperature working conditions prefer addition molding silicone resin
Recovery elasticity and heat aging resistance Excellent Excellent Excellent Generally Depends on repeated compression or heat aging requirements
Storage after mixing at room temperature 72 hours of placement allowed Not indicated After sulfurization, prone to dead material Shorter applicable period Depends on production rhythm and applicable period
Sensitivity to platinum catalyst poisoning Sensitive to As, Hg, Sn, N, P, S, etc. Sensitive to N, P, S, heavy metals, acetylene, vinyl, and PVC Varies by system Does not involve platinum Requires strict control of substrate and equipment contamination
Applicability for injection molding 适用于电脑按键、键盘保护罩、密封件、手机套等注射成型硅橡胶制品 适用于纺织涂层和玻璃纤维涂层 适用于模压和注射 适用于密封 Depends on product structure and molding method
Self-extinguishing property of glass fiber coating Reaches V0 grade after dilution Reaches V0 grade after dilution Not applicable Requires verification Requires verification based on actual dilution ratio and thickness
Storage period 120 days According to product data Varies by product Varies by product Requires management according to storage conditions
Why is it still necessary to conduct complete tests for compatibility with substrates and molding processes?
Our company's public information states that Product 9250-40B is used for injection molding silicone rubber products such as computer keypads and keyboard protectors, seals, and phone cases, as well as dilution and application on glass fiber surfaces, with self-extinguishing ability reaching V0 grade. However, when used in actual systems, there may still be:
Differences in substrate types, surface treatments, and temperature resistance.
Accuracy of A/B measurement, mixing uniformity, and vacuum degassing.
Injection machine, mold temperature, and exhaust design.
Matching of curing temperature, time, and product thickness.
Dilution ratio and compatibility of diluents.
Environmental cleanliness and control of platinum catalyst poisons.
The influence of pigments, additives and release agents on curing.
Self-extinguishing property, adhesion and insulation performance of glass fiber coatings.
Storage conditions and the activity of A/B components.
Consistency of curing among batches and product appearance.
Appearance semi-transparent or reaching the standard of short-term curing, but not proving the stability of long-term use, heat aging resistance or flame retardancy. Verification should be conducted using the complete formula, actual substrate and working conditions before use.
Which parameters should be confirmed when using product 9250-40B?
Parameter category Required information
Application direction Computer keypads, keyboard protective covers, seals, mobile phone cases, glass fiber surface coatings
Substrate type Plastic, metal, glass fiber, electronic components
Surface treatment Cleaning method, drying degree, presence of oil and release agents
A/B ratio 1:100, measurement accuracy and mixing uniformity
Defoaming process Vacuum defoaming conditions, time, vacuum degree
Injection/coating conditions Mold temperature, injection speed, pressure, coating thickness
Curing conditions Adjust temperature and time according to the thickness and size of the product
Dilution process Dilution ratio, diluent type, compatibility
Environmental cleanliness Avoid As, Hg, Sn, N, P, S, etc. platinum catalyst toxins
Storage conditions Light-proof, protection from direct sunlight, waterproof, fireproof, storage period 120 days
Acceptance indicators Appearance, density, hardness, tensile strength, elongation, tear strength, adhesion, self-extinguishing property
What should be verified when using product 9250-40B?
A/B measurement accuracy and mixing uniformity.
Vacuum defoaming effect and internal air bubbles in injection components/coatings.
Hardness, tensile strength, elongation and tear strength after curing.
Rebound, heat aging resistance and dimensional stability of injection components.
Adhesion between coating and glass fiber.
Self-extinguishing V0 condition of the glass fiber coating after dilution.
Influence of substrate, pigments and additives on platinum catalysts.
Performance stability at -40℃ and 250℃.
Flowability of the rubber mixture within 72 hours after mixing and curing activity.
Consistency of curing among batches and product appearance.
Activity and curing speed of A/B components within 120 days of storage.
Effectiveness of safe operation and ventilation protection.
How to design tests before using product 9250-40B?
Establish a current liquid silicone or coating benchmark, record model, A/B ratio, defoaming, injection/coating and curing conditions and failure performance.
Uniform test conditions: substrate, surface treatment, A/B ratio, defoaming process, mold temperature, injection speed, coating thickness, curing conditions.
Set candidate samples: current materials, product 9250-40B, different curing conditions or dilution ratio gradients.
Complete the full process tests: mixing → defoaming → injection/coating → curing → performance testing → heat aging/resistance verification.
Evaluate actual results: appearance, hardness, strength, elongation, tear strength, adhesion, self-extinguishing property, rebound.
Test items Uniform requirements
Substrate and surface treatment Consistent
A/B ratio 1:100
Defoaming process Consistent
Injection/coating conditions Set gradients according to the test design
Curing conditions Set gradients according to the test design
Dilution ratio Set gradients according to the test design
Measurement method Appearance, hardness, strength, elongation, tear strength, adhesion, self-extinguishing property consistent
Under which circumstances should product 9250-40B not be directly used?
A/B measurement accuracy cannot be guaranteed or mixing is not uniform, resulting in incomplete curing.
Substrate or the environment contains As, Hg, Sn, N, P, S, etc. platinum catalyst toxins, resulting in poor curing.
After more than 72 hours of mixing or improper storage temperature, the rubber mixture activity decreases.
Insufficient vacuum degassing results in residual air bubbles in the injection components or coatings, affecting appearance and performance.
The substrate has insufficient temperature resistance, and the curing temperature may damage the substrate or electronic components.
Specific food contact, medical or airworthiness approvals are required, but corresponding documentation has not been obtained yet.
There are clear dilution ratios and coating thickness requirements for self-extinguishing V0, but they have not been verified under actual conditions.
Only the application direction is known, without base material, A/B ratio, curing and injection/coating data.
The customer requests to directly mix it into the in-use system, but cannot control the ratio, degassing and curing conditions.
When switching from other liquid silicone or coatings, the dilution and curing processes have not been re-adjusted.
The storage conditions do not meet the requirements of avoiding light, waterproof and fireproof, or the storage period exceeds 120 days.
The injection machine or mold has cross-contamination, leading to platinum catalyst poisoning or batch fluctuations.
What selection support can our company provide?
As a provider of the entire organic silicone value chain solutions, our company can assist in comparing the applicability of injection/coating liquid silicone resins in different base materials, molding methods and curing conditions for product liquid silicone 9250-40B.
For projects such as computer keys, seals, phone cases or glass fiber coatings that need to balance resilience, heat aging resistance, dimensional stability and self-extinguishing properties, before selection, the following information should be provided:
Application direction and base material type.
Target hardness, resilience and heat aging requirements.
A/B ratio, degassing and curing conditions.
Injection machine, mold temperature, injection speed and coating thickness.
Dilution ratio and diluent type.
Compatibility of base material, pigments, additives and platinum catalyst.
Operating temperature, self-extinguishing V0 and adhesion requirements.
Current material model, ratio and failure performance.
Acceptance methods and applicable standards.
After receiving complete materials, it can be determined whether to prioritize testing a certain curing and dilution scheme of 9250-40B, or to choose other liquid silicone resins or coating materials route.
Common Misconceptions
The A/B ratio can have a slight deviation.
The usage ratio of product 9250-40B is 1:100. Deviation or uneven mixing can lead to incomplete curing or performance degradation. Precise measurement is required.
After mixing, it can be left at room temperature for 72 hours, and then production can be arranged freely.
72 hours is the upper limit for room temperature storage. Storage temperature, humidity, and contamination can affect the shelf life. It should be used under verified conditions.
The poisoning of platinum catalyst can be ignored.
Contact with compounds such as As, Hg, Sn, N, P, S can cause poor curing. It is necessary to strictly control the substrate, pigment, equipment, and environmental pollution.
Compatibility with the substrate allows for direct injection or coating.
It is still necessary to confirm surface cleanliness, A/B ratio, degassing, curing conditions, and pollutant control.
25℃ performance is the same, so it can be replaced in equal amounts.
Different liquid silicone resins have different curing characteristics, sensitivity to platinum catalyst, and molding adaptability. Replacement requires revalidation.
The dilution ratio does not affect self-extinguishing property.
The dilution ratio and coating thickness jointly affect the achievement of V0 self-extinguishing property. It is necessary to verify according to actual conditions.
Product 9250-40B can be used in all injection and coating scenarios.
This product is suitable for computer keypads, keyboard protectors, seals, phone cases, and fiberglass coatings. For systems with insufficient temperature resistance, platinum catalyst poisons or special flame retardant requirements, other materials may need to be selected.
It can still be used directly after 120 days of storage.
The storage period is 120 days. After expiration or improper storage, it is necessary to retest the activity and curing performance of the A/B components.
Recommended selection steps
Confirm the application direction: computer keypads, keyboard protectors, seals, phone cases, or fiberglass surface coatings.
Confirm the substrate type, surface treatment, and temperature resistance conditions.
Confirm the A/B ratio, mixing uniformity, and vacuum degassing process.
Confirm the injection/coating conditions, curing temperature, and product thickness.
Confirm the dilution ratio, diluent, and pigment compatibility.
Confirm the operating temperature, heat resistance aging, and self-extinguishing requirements.
Make a preliminary selection of product 9250-40B or other liquid silicone resins based on the application scenario.
Set up different curing conditions, dilution ratios, and coating thickness gradients for small tests.
Test appearance, hardness, strength, elongation, tear strength, and adhesion.
Perform heat resistance aging, low temperature, rebound, and self-extinguishing verification.
Evaluate the consistency of curing among batches and the appearance of the products.
Confirm that environmental cleanliness control (avoiding platinum catalyst poisons) is in place.
After completing multiple batch validations, determine the final usage plan.