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A Review of Literature Research on Dimethyl Silicone Oil

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Dimethyl silicone oil, as an important organic silicon compound, has shown wide application prospects in multiple fields due to its unique physical and chemical properties. This article reviews the synthesis methods, physicochemical properties, and applications of dimethyl silicone oil in various fields, and looks forward to its future development trends.
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1. Introduction
Dimethyl silicone oil, also known as polydimethylsiloxane, is a colorless, odorless, and non-toxic oily liquid. It has excellent properties such as high and low temperature resistance, oxidation resistance, shear resistance, low viscosity temperature coefficient, low surface tension, hydrophobicity, defoaming, demolding, electrical insulation, and physiological inertness. Therefore, it is widely used in many fields such as machinery, electrical engineering, textiles, coatings, medicine, etc.



2. Synthesis method

The synthesis methods of dimethyl silicone oil mainly include the following:

Acid catalysis method: Synthesis is carried out using octamethylcyclotetrasiloxane and hexamethyldisiloxane as raw materials and acid as a catalyst. Common solid acids include styrene divinylbenzene type macroporous strong acid cation exchange resin, sulfonation medium, and solid superacid. This method has a simple process, no pollution, and high product purity.
Alkaline catalysis method: using alkaline catalysts such as KOH or temporary catalysts (such as tetramethylammonium hydroxide) for catalytic equilibrium reaction to produce dimethyl silicone oil. This method is suitable for producing medium and high viscosity dimethyl silicone oil.
Other methods include co hydrolysis and condensation of dimethyldichlorosilane and trimethylchlorosilane, or condensation reaction of low molar polydimethylsiloxane diol with trimethylsilanol. However, due to the complex reaction process and low product purity, these methods are rarely used.

3. Physical and chemical properties
Dimethyl silicone oil has a series of unique physicochemical properties, including:

Low surface tension: When dimethyl silicone oil is used as an additive in coatings, oils, cosmetics, and other products, it can significantly improve leveling and smoothness.
High chemical inertness: This makes dimethyl silicone oil widely used in the medical field, such as as as a defoamer for gastrointestinal endoscopy and surgical procedures.
High and low temperature resistance: Dimethyl silicone oil can be used for a long time at temperatures ranging from -50 ℃ to+180 ℃, and even up to 200 ℃ in some inert gases.
Electrical insulation: Dimethyl silicone oil plays an important role as an insulating medium in the electrical industry.

4. Application Fields
Dimethyl silicone oil has a wide range of applications, including but not limited to:


Electrical industry: as an insulation medium that is resistant to temperature, arc, corrosion, and moisture.
Chemical industry: As an excellent heat carrier, it is used in processes such as synthetic resin and oil processing.
Mechanical industry: used for shock absorption, damping, lubrication, force transmission, etc. in precision machinery and instruments.
In the medical field, it is used as a defoamer for gastrointestinal bloating and pulmonary edema caused by various reasons, as well as a lubricant for gastrointestinal endoscopy.
In the field of daily chemical products: as an additive in cosmetics, it increases the comfort and luster of products.
Other fields: such as surface treatment agents used for processing optical instruments, medicine bottles, film, etc.

5. Development Trends and Prospects
With the advancement of technology and the development of industrialization, the application fields of dimethyl silicone oil will continue to expand. Especially in cutting-edge fields such as new energy, new materials, and biomedicine, dimethyl silicone oil is expected to play a greater role. Meanwhile, with the increasing awareness of environmental protection, green and environmentally friendly synthesis methods and applications will become an important direction for the future development of dimethyl silicone oil.


6. Conclusion
Dimethyl silicone oil, as an important organic silicon compound, has unique physical and chemical properties and broad application prospects. By continuously improving synthesis methods and expanding application areas, dimethyl silicone oil will play an important role in more fields, contributing to human technological progress and social development.

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